Plenary
Lecture
Field Assisted Processing of Polymer Nanocomposites with
Functionalized Carbon Nanotubes and Nanofibres
Professor Jose
M. Kenny
European Centre for Nanostructured Polymers
University of Perugia, Loc. Pentima Bassa 21, 05100
Terni-Italy
E-mail: jkenny@unipg.it
Abstract:
Light nanocomposite materials with exceptional
mechanical and electronic properties can be made using
different type of reinforcements and polymer matrices.
In particular, carbon nanotubes (CNT), and more recently
Carbon nanofibres (CNF) have been studied extensively
because of their exceptional mechanical and electrical
properties, yet their practical and extensive use in
commercial materials is still missing. The utilization
of CNTs and CNFs as reinforcement to design novel
composites has been object of many different approaches
in the last 10 years; however, there is a lack of a
knowledge based approach to achieve the
nanostructuration level required to optimize the CNT(CNF)/polymer
composite performances.
Currently, carbon nanoobjects are incorporated within
the polymer matrix by mixing into the polymer,
dispersion in solution or melt processing. However,
these methodologies present several critical issues as
for example the non-uniform dispersion of
nanoreinforcements within the polymer matrix and the
lack of control of the alignment or orientation of CNTs
and CNFs in the resulting composites. Generally, it is
difficult to disperse well a relative high concentration
of these nanoobjects into the polymer precursors because
of the viscosity of the polymers and the entanglement of
the nanotubes.
The challenge for the next future is to get innovative
polymer composites filled with CNTs and CNFs in order to
obtain nanostructured materials with tailor made
properties. For example, the isotropic conductivity of
the composites is not necessary in some cases. For
instance, it is demanded that the electron charge can
penetrate the antistatic shielding film as soon as
possible. The conductivity perpendicular to the film
surface should be as high as possible but the lateral
conductivity is not important—perfect conductivity along
one axis is enough to satisfy the application.
Our goal is to investigate the effects of electric and
magnetic fields on the physical properties of nanotube
based nanocomposites under static loading conditions. We
report here our results for different matrices:
poly(methyl methacrylate), epoxy systems, block
copolymers loaded with carbon nanotubes and carbon
nanofibres. The influence of orientation on the
electrical anisotropy as well as the role played by the
magnetic field on the rheological properties is also
reported. These results provide an initial understanding
of how electric and magnetic fields can be used to
control the bulk physical properties of such
nanocomposites.
Brief Biography of the Speaker:
Professor Jose M. Kenny was born in 1953 in Buenos Aires
(Argentina), where he got his PhD in Chemical
Engineering from the University of South (Bahia Blanca).
He is currently Full Professor of Material Science and
Technology at the University of Perugia, where he also
teaches Polymer Technology and Materials Nanotechnology.
Moreover, Prof. Kenny is the Director of the
International PhD Program on Materials Nanotechnology
coordinated by the University of Perugia in
collaboration with several European Universities and is
the Director of the European Master on Polymer
Nanotechnology organized by the University of Perugia.
Both programs are supported by the European Network of
Excellence "NANOFUN-POLY" coordinated by Prof. Kenny
through the Italian Consortium on Materials Science and
Technology (INSTM). Recently, Prof. Kenny has been
nominated President of the European Centre on
Nanostructured Polymers legally constituted in Florence
with the support of 12 European Research Centres (www.ecnp.eu.org).
During his career Prof. Kenny has been visiting and
research professor in the following universities:
University of Naples (1984-1991), University of
Connecticut: (1989) University of Washington (1990),
Washington University of Saint Louis (1991). He has
published more than 300 papers in the scientific
literature on the following subjects: mathematical
modelling of the processing of composites and polymers,
materials for aerospace applications and automotive
applications, mathematical modelling of reactive
processes, interfaces and surface treatments on
polymeric, metallic, ceramic and composite materials;
nanotechnologies of polymeric materials, processing and
characterization of carbon nanotubes and of their
polymer nanocomposites. Moreover, Prof. Kenny has
directed more than 100 theses in Materials Engineering
and 15 PhD theses on Industrial Engineering and
Materials Nanotechnology.
Prof. Kenny has coordinated several Italian and
international research projects is member of several
scientific societies and is currently Past-President of
the SAMPE Europe (Society for the Advancement of
Material and Process Engineering) and Vice-president of
SAMPE Italy. Recently, Prof. Kenny has been elected
member of the Board of the Italian Industrial
Association of Composite Materials.
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